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wolverine would slaughter captain america because not only is has he got over 100 years of combat experience to help him but cap couldn't hit him or he'd probably break his hand (metal skull remember?). the vibranium/adamantium shield wouldn't prove a problem either because of wolverines muramasa blade which slices at a molecular level therefore destroying caps shield. while cap is a brilliant tactician wolverine is not an idiot like everyone thinks because in the middle of a fight his brainwaves where described as the "equivalent of an Olympic-level gymnast performing a gold medal routine while simultaneously beating four chess computers in his head" by a mutant genius
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Cap would likely not break his hand on his metal skull simply because Wolverine is not immovable. Wolverine would likely move before Cap's hand broke.
The shield is not vibranium/adamantium. The shield is vibranium/steel. Adamantium was created in an effort to duplicate the material. I believe that the muramasa blade was used against Wolverine and didn't cut through his adamantium bones. So it wouldn't likely cut through the shield. Anyway, I think that he gave the blade away.
Not saying that Wolverine is an idiot but the comment was not in regards to Wolverine's ability to strategize. It was in regards to subconcious fighting skills. So the argument could be that once Wolverine loses control, he would be a better fighter than Captain America but not necessarily from the start. And I don't see why Captain America would chose a head to head fight any more than Batman would against Superman. Captain America would likely prepare for the fight ahead of time.